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Chemist Explains the Chemistry Behind Decaf Coffee
 
An anonymous reader quotes a report from The Conversation, written by Michael W. Crowder, Professor of Chemistry and Biochemistry and Dean of the Graduate School at Miami University: For many people, the aroma of freshly brewed coffee is the start of a great day. But caffeine can cause headaches and jitters in others. That's why many people reach for a decaffeinated cup instead. I'm a chemistry professor who has taught lectures on why chemicals dissolve in some liquids but not in others. The processes of decaffeination offer great real-life examples of these chemistry concepts. Even the best decaffeination method, however, does not remove all of the caffeine -- about 7 milligrams of caffeine usually remain in an 8-ounce cup. Producers decaffeinating their coffee want to remove the caffeine while retaining all -- or at least most -- of the other chemical aroma and flavor compounds. Decaffeination has a rich history, and now almost all coffee producers use one of three common methods. All these methods, which are also used to make decaffeinated tea, start with green, or unroasted, coffee beans that have been premoistened. Using roasted coffee beans would result in a coffee with a very different aroma and taste because the decaffeination steps would remove some flavor and odor compounds produced during roasting. Here's a summary of each method discussed by Dr. Crowder: The Carbon Dioxide Method: Developed in the early 1970s, the carbon dioxide method uses high-pressure CO2 to extract caffeine from moistened coffee beans, resulting in coffee that retains most of its flavor. The caffeine-laden CO2 is then filtered out using water or activated carbon, removing 96% to 98% of the caffeine with minimal CO2 residue. The Swiss Water Process: First used commercially in the early 1980s, the Swiss water method uses hot water and activated charcoal filters to decaffeinate coffee, preserving most of its natural flavor. This chemical-free approach removes 94% to 96% of the caffeine by soaking the beans repeatedly until the desired caffeine level is achieved. Solvent-Based Methods: Originating in the early 1900s, solvent-based methods use organic solvents like ethyl acetate and methylene chloride to extract caffeine from green coffee beans. These methods remove 96% to 97% of the caffeine through either direct soaking in solvent or indirect treatment of water containing caffeine, followed by steaming and roasting to ensure safety and flavor retention. "It's chemically impossible to dissolve out only the caffeine without also dissolving out other chemical compounds in the beans, so decaffeination inevitably removes some other compounds that contribute to the aroma and flavor of your cup of coffee," writes Dr. Crowder in closing. "But some techniques, like the Swiss water process and the indirect solvent method, have steps that may reintroduce some of these extracted compounds. These approaches probably can't return all the extra compounds back to the beans, but they may add some of the flavor compounds back."

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Oracle's Java Pricing Brews Bitter Taste, Subscribers Spill Over To OpenJDK
 
Lindsay Clark reports via The Register: Only 14 percent of Oracle Java subscribers plan to stay on Big Red's runtime environment, according to a study following the introduction of an employee-based subscription model. At the same time, 36 percent of the 663 Java users questioned said they had already moved to the employee-based pricing model introduced in January 2023. Shortly after the new model was implemented, experts warned that it would create a significant price hike for users adopting it. By July, global tech research company Gartner was forecasting that those on the new subscription package would face between two and five times the costs compared with the previous usage-based model. As such, among the 86 percent of respondents using Oracle Java SE who are currently moving or plan to move all or some of their Java applications off Oracle environments, 53 percent said the Oracle environment was too expensive, according to the study carried out by independent market research firm Dimensional Research. Forty-seven percent said the reason for moving was a preference for open source, and 38 percent said it was because of uncertainty created by ongoing changes in pricing, licensing, and support. [...] To support OpenJDK applications in production, 46 percent chose a paid-for platform such as Belsoft Liberica, IBM Semeru, or Azul Platform Core; 45 percent chose a free supported platform such as Amazon Corretto or Microsoft Build of OpenJDK; and 37 percent chose a free, unsupported platform. Of the users who have already moved to OpenJDK, 25 percent said Oracle had been significantly more expensive, while 41 percent said Big Red's licensing had made it somewhat more expensive than the alternative. The survey found three-quarters of Java migrations were completed within a year, 23 percent within three months.

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A Hacker 'Ghost' Network Is Quietly Spreading Malware on GitHub
 
Researchers at Check Point have uncovered a clandestine network of approximately 3,000 "ghost" accounts on GitHub, manipulating the platform to promote malicious content. Since June 2023, a cybercriminal dubbed "Stargazer Goblin" has been exploiting GitHub's community features to boost malicious repositories, making them appear legitimate and popular. Antonis Terefos, a malware reverse engineer at Check Point, discovered the network's activities, which include "starring," "forking," and "watching" malicious pages to increase their visibility and credibility. The network, named "Stargazers Ghost Network," primarily targets Windows users, offering downloads of seemingly legitimate software tools while spreading various types of ransomware and info-stealer malware.

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